Chemistry

Chemistry

Problem

For the equilibrium 2 HI(g) ⇌ H2_2(g) + I2_2(g) at 700 K, Kc=0.016K_c = 0.016. At t=30 t = 30\,s the measured concentrations are [HI] = 0.20 M, [H2_2] = 0.040 M, and [I2_2] = 0.040 M. Calculate QcQ_c at this moment and state whether the reaction mixture will shift toward reactants or products as it moves toward equilibrium.
Intuitive explanation

The key is to recognize that QcQ_c is the reaction quotient—it's just like KcK_c, but calculated with the current concentrations rather than equilibrium ones. By comparing QcQ_c to KcK_c, you can predict which direction the system will shift: if QcQ_c is too large, the system has too many products and must shift left (toward reactants); if QcQ_c is too small, it must shift right (toward products). Calculate QcQ_c using the same expression as KcK_c, then compare the two numbers to determine the direction.

Intuitive explanation

The key is to recognize that QcQ_c is the reaction quotient—it's just like KcK_c, but calculated with the current concentrations rather than equilibrium ones. By comparing QcQ_c to KcK_c, you can predict which direction the system will shift: if QcQ_c is too large, the system has too many products and must shift left (toward reactants); if QcQ_c is too small, it must shift right (toward products). Calculate QcQ_c using the same expression as KcK_c, then compare the two numbers to determine the direction.

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