Chemistry
Chemistry
Problem
For the equilibrium 2 HI(g) ⇌ H(g) + I(g) at 700 K, . At s the measured concentrations are [HI] = 0.20 M, [H] = 0.040 M, and [I] = 0.040 M. Calculate at this moment and state whether the reaction mixture will shift toward reactants or products as it moves toward equilibrium.Intuitive explanation
The key is to recognize that is the reaction quotient—it's just like , but calculated with the current concentrations rather than equilibrium ones. By comparing to , you can predict which direction the system will shift: if is too large, the system has too many products and must shift left (toward reactants); if is too small, it must shift right (toward products). Calculate using the same expression as , then compare the two numbers to determine the direction.
Intuitive explanation
The key is to recognize that is the reaction quotient—it's just like , but calculated with the current concentrations rather than equilibrium ones. By comparing to , you can predict which direction the system will shift: if is too large, the system has too many products and must shift left (toward reactants); if is too small, it must shift right (toward products). Calculate using the same expression as , then compare the two numbers to determine the direction.