Chemistry

Chemistry

Problem

At 25 °C, the concentration of H+\text{H}^+ ions in 1.00×10−31.00 \times 10^{-3} M aqueous solution of a weak monobasic acid having acid dissociation constant (KaK_a) of 4.00×10−114.00 \times 10^{-11} is X×10−7X \times 10^{-7} M. The value of XX is _____. Use: Ionic product of water (KwK_w) = 1.00×10−141.00 \times 10^{-14} at 25 °C
Intuitive explanation

This problem tests whether you recognize that an extremely weak acid (tiny KaK_a) barely dissociates, so the H+\text{H}^+ ions come almost entirely from water's autoionization, not the acid itself. Set up the equilibrium expression for the acid, but notice that KaK_a is so small that you can assume nearly all the acid remains undissociated—this lets you solve without the quadratic formula. The key insight is that in such a dilute, weakly acidic solution, water's contribution to H+\text{H}^+ becomes significant and must be accounted for carefully.

Intuitive explanation

This problem tests whether you recognize that an extremely weak acid (tiny KaK_a) barely dissociates, so the H+\text{H}^+ ions come almost entirely from water's autoionization, not the acid itself. Set up the equilibrium expression for the acid, but notice that KaK_a is so small that you can assume nearly all the acid remains undissociated—this lets you solve without the quadratic formula. The key insight is that in such a dilute, weakly acidic solution, water's contribution to H+\text{H}^+ becomes significant and must be accounted for carefully.

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