Chemistry
Chemistry
Problem
At 25 °C, the concentration of ions in M aqueous solution of a weak monobasic acid having acid dissociation constant () of is M. The value of is _____. Use: Ionic product of water () = at 25 °CIntuitive explanation
This problem tests whether you recognize that an extremely weak acid (tiny ) barely dissociates, so the ions come almost entirely from water's autoionization, not the acid itself. Set up the equilibrium expression for the acid, but notice that is so small that you can assume nearly all the acid remains undissociated—this lets you solve without the quadratic formula. The key insight is that in such a dilute, weakly acidic solution, water's contribution to becomes significant and must be accounted for carefully.
Intuitive explanation
This problem tests whether you recognize that an extremely weak acid (tiny ) barely dissociates, so the ions come almost entirely from water's autoionization, not the acid itself. Set up the equilibrium expression for the acid, but notice that is so small that you can assume nearly all the acid remains undissociated—this lets you solve without the quadratic formula. The key insight is that in such a dilute, weakly acidic solution, water's contribution to becomes significant and must be accounted for carefully.