JEE Advanced 2017 Paper 2 Chemistry Q17

Chemistry · Substitution & Elimination · Aromatic Substitution · Aldehydes & Ketones

Problem

Read the following paragraph and answer Q.17 and Q.18. The reaction of compound P with CHX3MgBr\ce{CH3MgBr} (excess) in (CX2HX5)X2O\ce{(C2H5)2O} followed by addition of HX2O\ce{H2O} gives Q. The compound Q on treatment with HX2SOX4\ce{H2SO4} at 0 ∘C0\,^{\circ}\mathrm{C} gives R. The reaction of R with CHX3COCl\ce{CH3COCl} in the presence of anhydrous AlClX3\ce{AlCl3} in CHX2ClX2\ce{CH2Cl2} followed by treatment with HX2O\ce{H2O} produces compound S. [Et in compound P is ethyl group] The product S is

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