Chemistry

Chemistry

Problem

An aqueous solution contains 10% ammonia by mass and has a density of 0.99 g cm−30.99 \text{ g cm}^{-3} . Calculate hydroxyl and hydrogen ion concentration in this solution. KaK_a for NH4+NH_4^+ = 5.0×10−10M5.0 \times 10^{-10} M .
Intuitive explanation

Ammonia solutions are weakly basic because NH3NH_3 accepts protons from water, establishing an equilibrium. The key is to first find the molarity of ammonia from the mass percentage and density, then use the KbK_b relationship (derived from KwK_w and the given KaK_a) to find [OH−][OH^-] from the weak base equilibrium. Once you have [OH−][OH^-], finding [H+][H^+] is just one step using the water ionization constant.

Intuitive explanation

Ammonia solutions are weakly basic because NH3NH_3 accepts protons from water, establishing an equilibrium. The key is to first find the molarity of ammonia from the mass percentage and density, then use the KbK_b relationship (derived from KwK_w and the given KaK_a) to find [OH−][OH^-] from the weak base equilibrium. Once you have [OH−][OH^-], finding [H+][H^+] is just one step using the water ionization constant.

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