Chemistry

Chemistry

Problem

2, 4-dinitrophenol ( pKa=4\text{p}K_a = 4 ) acts as buffer and if pH of this buffer is adjusted to 5, the ratio of concentration of dissociated and undissociated molecules of 2, 4-dinitrophenol is : a. 1 b. 10 c. 0.1 d. 0.01
Intuitive explanation

The key here is the Henderson-Hasselbalch equation, which relates pH, pKapK_a, and the ratio of dissociated to undissociated forms of a weak acid. When pH differs from pKapK_a, this ratio tells you which form dominates—and by how much. Since your pH is one unit above the pKapK_a, the dissociated form will outnumber the undissociated form by a predictable factor that depends only on that difference.

Intuitive explanation

The key here is the Henderson-Hasselbalch equation, which relates pH, pKapK_a, and the ratio of dissociated to undissociated forms of a weak acid. When pH differs from pKapK_a, this ratio tells you which form dominates—and by how much. Since your pH is one unit above the pKapK_a, the dissociated form will outnumber the undissociated form by a predictable factor that depends only on that difference.

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