Introduction to Quantum Mechanics · Problem 4.29

Quantum Mechanics in Three Dimensions — David J. Griffiths

Physics — Quantum Mechanics · spin_matrices

Problem

Problem 4.29 (a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134. (b) Show that the Pauli spin matrices (Equation 4.148) satisfy the product rule σjσk=δjk+i∑lϵjklσl\sigma_j \sigma_k = \delta_{jk} + i \sum_l \epsilon_{jkl} \sigma_l, (4.153) where the indices stand for xx, yy, or zz, and ϵjkl\epsilon_{jkl} is the Levi-Civita symbol: +1+1 if jkl=123,231jkl = 123, 231, or 312312; −1-1 if jkl=132,213jkl = 132, 213, or 321321; 00 otherwise.
Intuitive explanation

Spin matrices encode angular momentum through their commutation structure—the same algebraic rules that govern rotations in ordinary space also govern spin rotations in quantum mechanics. Part (a) asks you to verify that [S^j,S^k]=iℏϵjklS^l[\hat{S}_j, \hat{S}_k] = i\hbar \epsilon_{jkl} \hat{S}_l by direct matrix multiplication; part (b) then reveals the elegant underlying pattern by showing that the Pauli matrices themselves (which are S^\hat{S} up to factors of ℏ/2\hbar/2) satisfy a closed product rule that automatically generates both the identity and the commutation relations. This product rule is the key: it tells you exactly what happens when you multiply any two Pauli matrices, making the algebra transparent.

Intuitive explanation

Spin matrices encode angular momentum through their commutation structure—the same algebraic rules that govern rotations in ordinary space also govern spin rotations in quantum mechanics. Part (a) asks you to verify that [S^j,S^k]=iℏϵjklS^l[\hat{S}_j, \hat{S}_k] = i\hbar \epsilon_{jkl} \hat{S}_l by direct matrix multiplication; part (b) then reveals the elegant underlying pattern by showing that the Pauli matrices themselves (which are S^\hat{S} up to factors of ℏ/2\hbar/2) satisfy a closed product rule that automatically generates both the identity and the commutation relations. This product rule is the key: it tells you exactly what happens when you multiply any two Pauli matrices, making the algebra transparent.

Related theory

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