Blundell Thermal Physics · Problem 11.2
Energy
Physics — Statistical Mechanics · heat-capacity-ratio-ideal-gas
Problem
Show that, for an ideal gas, and where and are the heat capacities per mole.Intuitive explanation
The key is recognizing that is defined by the ratio of heat capacities, and that the first law of thermodynamics gives you a direct relationship between them. For an ideal gas, always holds—this comes from the work done during constant-pressure heating. Once you use this constraint along with the definition of , you can algebraically manipulate these two equations to isolate in terms of and , yielding both identities.
Intuitive explanation
The key is recognizing that is defined by the ratio of heat capacities, and that the first law of thermodynamics gives you a direct relationship between them. For an ideal gas, always holds—this comes from the work done during constant-pressure heating. Once you use this constraint along with the definition of , you can algebraically manipulate these two equations to isolate in terms of and , yielding both identities.