Chemistry

Chemistry

Problem

The chief reaction(s) occurring in blast furnace during extraction of iron from haematite is/are : a. Fe2O3+3CO⟶2Fe+3CO2\text{Fe}_2\text{O}_3 + 3\text{CO} \longrightarrow 2\text{Fe} + 3\text{CO}_2 b. FeO+SiO2⟶FeSiO3\text{FeO} + \text{SiO}_2 \longrightarrow \text{FeSiO}_3 c. Fe2O3+C⟶2Fe+3CO\text{Fe}_2\text{O}_3 + \text{C} \longrightarrow 2\text{Fe} + 3\text{CO} d. CaO+SiO2⟶CaSiO3\text{CaO} + \text{SiO}_2 \longrightarrow \text{CaSiO}_3
Intuitive explanation

Iron extraction in a blast furnace is fundamentally about reduction—removing oxygen from iron oxide using carbon monoxide as the reducing agent. The key insight is that the furnace creates a temperature gradient where different reactions dominate at different heights: at the hottest zone near the bottom, CO\text{CO} is regenerated from CO2\text{CO}_2 and reduces iron oxide directly, while higher up, CO2\text{CO}_2 itself acts as the oxidizing agent. Understanding which species (CO\text{CO} vs CO2\text{CO}_2) is the actual reducing agent at each stage, and why the furnace design maintains this chemical gradient, is what unlocks the answer.

Intuitive explanation

Iron extraction in a blast furnace is fundamentally about reduction—removing oxygen from iron oxide using carbon monoxide as the reducing agent. The key insight is that the furnace creates a temperature gradient where different reactions dominate at different heights: at the hottest zone near the bottom, CO\text{CO} is regenerated from CO2\text{CO}_2 and reduces iron oxide directly, while higher up, CO2\text{CO}_2 itself acts as the oxidizing agent. Understanding which species (CO\text{CO} vs CO2\text{CO}_2) is the actual reducing agent at each stage, and why the furnace design maintains this chemical gradient, is what unlocks the answer.

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