Chemistry

Chemistry

Problem

Which of the following is the correct ground-state electron configuration, in noble-gas notation, for silver (atomic number 47)? a) [Kr]4d9 5s2[\text{Kr}]4d^{9}\,5s^{2} b) [Kr]4d10 5p1[\text{Kr}]4d^{10}\,5p^{1} c) [Kr]4d10 5s1[\text{Kr}]4d^{10}\,5s^{1} d) [Kr]4d10 5s2[\text{Kr}]4d^{10}\,5s^{2}
Intuitive explanation

Silver is a transition metal, so its electron configuration involves filling the dd orbitals—but here's the key: silver actually has a filled dd subshell, which is unusually stable. Rather than following the expected pattern, silver "steals" an electron from the ss orbital to complete its dd block, giving it a half-filled or full dd configuration. Use the noble-gas notation by starting with the nearest noble gas below silver, then carefully account for which orbitals fill and in what order.

Intuitive explanation

Silver is a transition metal, so its electron configuration involves filling the dd orbitals—but here's the key: silver actually has a filled dd subshell, which is unusually stable. Rather than following the expected pattern, silver "steals" an electron from the ss orbital to complete its dd block, giving it a half-filled or full dd configuration. Use the noble-gas notation by starting with the nearest noble gas below silver, then carefully account for which orbitals fill and in what order.

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