Chemistry

Chemistry

Problem

Number of mole of K2Cr2O7\text{K}_2\text{Cr}_2\text{O}_7 in acidic medium required to oxidise one mole of Cu3P\text{Cu}_3\text{P} to CuSO4\text{CuSO}_4 and H3PO4\text{H}_3\text{PO}_4 is : a. 11/6 b. 6/11 c. 3/5 d. 5/3
Intuitive explanation

This is a redox problem where you need to track electron transfer carefully. Cu3P\text{Cu}_3\text{P} contains copper in the +1 state and phosphorus in the −3 state—both are reducing agents. You must oxidize both elements to their final products (Cu2+\text{Cu}^{2+} and P5+\text{P}^{5+}), count the total electrons lost, then use the reduction of dichromate (Cr6+→Cr3+\text{Cr}^{6+} \to \text{Cr}^{3+}) to find how many moles of K2Cr2O7\text{K}_2\text{Cr}_2\text{O}_7 are needed.

Intuitive explanation

This is a redox problem where you need to track electron transfer carefully. Cu3P\text{Cu}_3\text{P} contains copper in the +1 state and phosphorus in the −3 state—both are reducing agents. You must oxidize both elements to their final products (Cu2+\text{Cu}^{2+} and P5+\text{P}^{5+}), count the total electrons lost, then use the reduction of dichromate (Cr6+→Cr3+\text{Cr}^{6+} \to \text{Cr}^{3+}) to find how many moles of K2Cr2O7\text{K}_2\text{Cr}_2\text{O}_7 are needed.

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