Chemistry

Chemistry

Problem

A vessel of volume 5 litre contains 1.4 g of nitrogen at a temperature 1800 K1800 \text{ K} . Find the pressure of the gas if 30% of its molecules are dissociated into atom at this temperature.
Intuitive explanation

The key here is that dissociation increases the total number of gas particles, which directly increases pressure. Start by finding how many moles of N2\text{N}_2 you have, then account for the fact that 30% breaks apart into individual N atoms—each N2\text{N}_2 molecule that dissociates becomes 2 atoms, so the particle count jumps. Once you know the total number of moles of gas particles present, use the ideal gas law PV=nRTPV = nRT to find pressure.

Intuitive explanation

The key here is that dissociation increases the total number of gas particles, which directly increases pressure. Start by finding how many moles of N2\text{N}_2 you have, then account for the fact that 30% breaks apart into individual N atoms—each N2\text{N}_2 molecule that dissociates becomes 2 atoms, so the particle count jumps. Once you know the total number of moles of gas particles present, use the ideal gas law PV=nRTPV = nRT to find pressure.

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