Irodov Problem 6.121

Physics · modern-physics

Problem

Making use of the Hund rules, find the number of electrons in the only partially filled subshell of the atom whose basic term is (a) 3F2; (b) 2P312; (c) 685/2.
Intuitive explanation

The key is to reverse-engineer the electron configuration from the term symbol 2S+1LJ^{2S+1}L_J. Extract the multiplicity to find total spin SS, use the letter to identify orbital angular momentum LL, then apply Hund's rules (maximize SS first, then LL, then determine JJ) to count electrons in the partially filled subshell. Each subshell has a maximum capacity that constrains your answer—you're looking for the unique electron count that produces exactly that term as the ground state.

Intuitive explanation

The key is to reverse-engineer the electron configuration from the term symbol 2S+1LJ^{2S+1}L_J. Extract the multiplicity to find total spin SS, use the letter to identify orbital angular momentum LL, then apply Hund's rules (maximize SS first, then LL, then determine JJ) to count electrons in the partially filled subshell. Each subshell has a maximum capacity that constrains your answer—you're looking for the unique electron count that produces exactly that term as the ground state.

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