Chemistry

Chemistry

Problem

30 mL of a solution containing 9.15 g/litre of an oxalate KxHy(C2O4)z⋅nH2O\text{K}_x\text{H}_y(\text{C}_2\text{O}_4)_z \cdot n\text{H}_2\text{O} are required for titrating 27 mL of 0.12N NaOH\text{NaOH} and 36 mL of 0.12 N KMnO4\text{KMnO}_4 separately. Calculate X,Y,ZX, Y, Z and nn . Assume all H-atoms are replaceable and X,Y,ZX, Y, Z are in the simple ratio of g-atoms.
Intuitive explanation

The key is recognizing that the oxalate compound's formula contains replaceable hydrogens, and you can determine how many through two independent titrations that probe different chemical properties. The NaOH titration reveals total acidity (all replaceable H atoms), while the permanganate titration exploits the reducing power of the oxalate ion itself—these two pieces of information, combined with the given mass concentration, uniquely constrain the formula. Work through the equivalents from each reaction to find the molar mass, then use that to deduce xx, yy, and zz from the stoichiometry.

Intuitive explanation

The key is recognizing that the oxalate compound's formula contains replaceable hydrogens, and you can determine how many through two independent titrations that probe different chemical properties. The NaOH titration reveals total acidity (all replaceable H atoms), while the permanganate titration exploits the reducing power of the oxalate ion itself—these two pieces of information, combined with the given mass concentration, uniquely constrain the formula. Work through the equivalents from each reaction to find the molar mass, then use that to deduce xx, yy, and zz from the stoichiometry.

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