Chemistry

Chemistry

Problem

The magnetic moment of [MnX4]2−[\text{MnX}_4]^{2-} is 5.9 BM. The geometry of the complex ion is : (XX = monodentate halide ion) a. tetrahedral b. square planar c. both are possible d. none of these
Intuitive explanation

The magnetic moment tells you how many unpaired electrons are in the complex—use the formula μ=n(n+2)\mu = \sqrt{n(n+2)} BM, where nn is the number of unpaired electrons. Work backwards from 5.9 BM to find nn, then determine which d-orbital configuration of Mn matches that count. Finally, consider whether the ligand (a halide, a weak-field ligand) causes pairing or leaves electrons unpaired, which reveals the geometry: tetrahedral complexes typically remain high-spin with weak-field ligands, while square planar or octahedral geometries might pair electrons differently.

Intuitive explanation

The magnetic moment tells you how many unpaired electrons are in the complex—use the formula μ=n(n+2)\mu = \sqrt{n(n+2)} BM, where nn is the number of unpaired electrons. Work backwards from 5.9 BM to find nn, then determine which d-orbital configuration of Mn matches that count. Finally, consider whether the ligand (a halide, a weak-field ligand) causes pairing or leaves electrons unpaired, which reveals the geometry: tetrahedral complexes typically remain high-spin with weak-field ligands, while square planar or octahedral geometries might pair electrons differently.

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