Chemistry
Chemistry
Problem
The equilibrium constant for is 4.3 at 450 K and 0.92 at 650 K. Determine the sign (positive or negative) of for the reaction.Intuitive explanation
The equilibrium constant changes dramatically with temperature—this is your clue to the reaction's enthalpy. When decreases as temperature increases, the equilibrium shifts toward reactants at higher , which only happens in an exothermic reaction (one that releases heat). Use Le Chatelier's principle: raising temperature favors the endothermic direction, so if the forward reaction is exothermic, higher pushes equilibrium backward, shrinking .
Intuitive explanation
The equilibrium constant changes dramatically with temperature—this is your clue to the reaction's enthalpy. When decreases as temperature increases, the equilibrium shifts toward reactants at higher , which only happens in an exothermic reaction (one that releases heat). Use Le Chatelier's principle: raising temperature favors the endothermic direction, so if the forward reaction is exothermic, higher pushes equilibrium backward, shrinking .