Chemistry

Chemistry

Problem

The equilibrium constant for CO(g)+Cl2(g)⇌COCl2(g)\mathrm{CO(g) + Cl_2(g) \rightleftharpoons COCl_2(g)} is 4.3 at 450 K and 0.92 at 650 K. Determine the sign (positive or negative) of ΔH\Delta H for the reaction.
Intuitive explanation

The equilibrium constant changes dramatically with temperature—this is your clue to the reaction's enthalpy. When KK decreases as temperature increases, the equilibrium shifts toward reactants at higher TT, which only happens in an exothermic reaction (one that releases heat). Use Le Chatelier's principle: raising temperature favors the endothermic direction, so if the forward reaction is exothermic, higher TT pushes equilibrium backward, shrinking KK.

Intuitive explanation

The equilibrium constant changes dramatically with temperature—this is your clue to the reaction's enthalpy. When KK decreases as temperature increases, the equilibrium shifts toward reactants at higher TT, which only happens in an exothermic reaction (one that releases heat). Use Le Chatelier's principle: raising temperature favors the endothermic direction, so if the forward reaction is exothermic, higher TT pushes equilibrium backward, shrinking KK.

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