The electron affinities (EA) of fluorine and chlorine are given below.
Element
EA (kJ mol−1)
F
−328
Cl
−349
Although fluorine is more electronegative than chlorine, its EA is less exothermic.
a. Part 1: Describe the general trend one would predict for EA values moving down Group 17 and state how the data for F and Cl deviate from that trend.
b. Part 2: Offer two distinct, well-supported reasons that account for the less exothermic EA of fluorine compared with chlorine.