A chemist runs four trials of the reaction C→products and records the following initial conditions and rates:
• Trial 1: [C]0=0.20M, T=298K, stirring on, rate = 0.015Ms−1
• Trial 2: [C]0=0.20M, T=308K, stirring on, rate = 0.031Ms−1
• Trial 3: [C]0=0.10M, T=308K, stirring on, rate = 0.015Ms−1
• Trial 4: [C]0=0.20M, T=298K, stirring off, rate = 0.010Ms−1
To evaluate the hypothesis that raising temperature doubles the rate by increasing the fraction of effective collisions, which pair of trials should the chemist compare to minimize confounding variables?
a) Trials 1 and 3
b) Trials 1 and 4
c) Trials 1 and 2
d) Trials 2 and 3