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Chemistry
Chemistry
Problem
Represent the voltaic cell obtained by coupling a lead half-cell,
Pb
(
s
)
∣
Pb
2
+
(
aq
)
\text{Pb}(\text{s}) \mid \text{Pb}^{2+}(\text{aq})
Pb
(
s
)
∣
Pb
2
+
(
aq
)
, and a silver half-cell,
Ag
(
s
)
∣
Ag
+
(
aq
)
\text{Ag}(\text{s}) \mid \text{Ag}^{+}(\text{aq})
Ag
(
s
)
∣
Ag
+
(
aq
)
. The standard reduction potentials of these electrodes are:
E
Pb
2
+
∣
Pb
⊖
=
−
0.13
V
,
E
Ag
+
∣
Ag
⊖
=
+
0.80
V
.
E_{\text{Pb}^{2+}|\text{Pb}}^{\ominus} = -0.13\text{ V}, E_{\text{Ag}^{+}|\text{Ag}}^{\ominus} = +0.80\text{ V}.
E
Pb
2
+
∣
Pb
⊖
=
−
0.13
V
,
E
Ag
+
∣
Ag
⊖
=
+
0.80
V
.
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