Physics

Physics · thermodynamics

Problem

Suppose we have a non-ideal gas, and in a certain volume range and temperature range, it is found to satisfy the state relation p=AVαTβp=A V^{\alpha} T^{\beta} where AA is a constant, α=−45\alpha=-\frac{4}{5} and β=32\beta=\frac{3}{2}, and the other variables have their usual meanings. Throughout the problem, we will assume to be always in that volume and temperature range. Assume that γ=CpCV\gamma=\frac{C_{p}}{C_{V}} is found to be constant for this gas ( γ\gamma is independent of the state of the gas), where CpC_{p} and CvC_{v} are the heat capacities at constant pressure and volume, respectively. What is the minimum possible value for γ\gamma ? Given constants: - Proton mass, mp=1.67⋅10−27 kgm_{p}=1.67 \cdot 10^{-27} \mathrm{~kg} - Neutron mass, mn=1.67⋅10−27 kgm_{n}=1.67 \cdot 10^{-27} \mathrm{~kg} - Electron mass, me=9.11⋅10−31 kgm_{e}=9.11 \cdot 10^{-31} \mathrm{~kg} - Avogadro's constant, N0=6.02⋅1023 mol−1N_{0}=6.02 \cdot 10^{23} \mathrm{~mol}^{-1} - Universal gas constant, R=8.31 J/(mol⋅K)R=8.31 \mathrm{~J} /(\mathrm{mol} \cdot \mathrm{K}) - Boltzmann's constant, kB=1.38⋅10−23 J/Kk_{B}=1.38 \cdot 10^{-23} \mathrm{~J} / \mathrm{K} - Electron charge magnitude, e=1.60⋅10−19Ce=1.60 \cdot 10^{-19} \mathrm{C} - 1 electron volt, 1eV=1.60⋅10−19 J1 \mathrm{eV}=1.60 \cdot 10^{-19} \mathrm{~J} - Speed of light, c=3.00⋅108 m/sc=3.00 \cdot 10^{8} \mathrm{~m} / \mathrm{s} - Universal Gravitational constant, G=6.67⋅10−11( N⋅m2)/kg2G=6.67 \cdot 10^{-11}\left(\mathrm{~N} \cdot \mathrm{m}^{2}\right) / \mathrm{kg}^{2} - Solar Mass M⊙=1.988⋅1030 kgM_{\odot}=1.988 \cdot 10^{30} \mathrm{~kg} - Acceleration due to gravity, g=9.8 m/s2g=9.8 \mathrm{~m} / \mathrm{s}^{2} - 1 unified atomic mass unit, 1u=1.66⋅10−27 kg=931MeV/c21 \mathrm{u}=1.66 \cdot 10^{-27} \mathrm{~kg}=931 \mathrm{MeV} / \mathrm{c}^{2} - Planck's constant, h=6.63⋅10−34 J⋅s=4.41⋅10−15eV⋅sh=6.63 \cdot 10^{-34} \mathrm{~J} \cdot \mathrm{s}=4.41 \cdot 10^{-15} \mathrm{eV} \cdot \mathrm{s} - Permittivity of free space, ϵ0=8.85⋅10−12C2/(N⋅m2)\epsilon_{0}=8.85 \cdot 10^{-12} \mathrm{C}^{2} /\left(\mathrm{N} \cdot \mathrm{m}^{2}\right) - Coulomb's law constant, k=14πϵ0=8.99⋅109( N⋅m2)/C2k=\frac{1}{4 \pi \epsilon_{0}}=8.99 \cdot 10^{9}\left(\mathrm{~N} \cdot \mathrm{m}^{2}\right) / \mathrm{C}^{2} - Permeability of free space, μ0=4π⋅10−7 T⋅m/A\mu_{0}=4 \pi \cdot 10^{-7} \mathrm{~T} \cdot \mathrm{m} / \mathrm{A} - Magnetic constant, μ04π=1⋅10−7( T⋅m)/A\frac{\mu_{0}}{4 \pi}=1 \cdot 10^{-7}(\mathrm{~T} \cdot \mathrm{m}) / \mathrm{A} - 1 atmospheric pressure, 1 atm=1.01⋅105 N/m2=1.01⋅105 Pa1 \mathrm{~atm}=1.01 \cdot 10^{5} \mathrm{~N} / \mathrm{m}^{2}=1.01 \cdot 10^{5} \mathrm{~Pa} - Wien's displacement constant, b=2.9b=2.9. 10−3 m⋅K10^{-3} \mathrm{~m} \cdot \mathrm{K} - Stefan-Boltzmann constant, σ=5.67⋅10−8 W/m2/K4\sigma=5.67 \cdot 10^{-8} \mathrm{~W} / \mathrm{m}^{2} / \mathrm{K}^{4}

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