Chemistry

Chemistry

Problem

Consider the two hypothetical elementary reactions below. • Reaction X: breaks two C–H bonds (bond energy ≈ 410 kJ mol⁻¹ each) and forms one C=C bond (bond energy ≈ 610 kJ mol⁻¹). • Reaction Y: breaks one C–C bond (bond energy ≈ 350 kJ mol⁻¹) and forms two C–H bonds (bond energy ≈ 410 kJ mol⁻¹ each). Which statement is most consistent with these bond-energy data? a) Reaction Y is more likely to be endothermic because breaking a C–C bond requires more energy than is released when forming C–H bonds b) Reaction X is more likely to be exothermic because forming a C=C bond releases more energy than breaking two C–H bonds requires c) Reaction Y is neither endothermic nor exothermic because the energies for breaking and forming bonds are approximately equal d) Reaction X is more likely to be endothermic because the energy required to break bonds exceeds the energy released when new bonds form

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