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Chemistry
Chemistry
Problem
A cell is to be constructed to show a redox change :
Cr
+
2
Cr
3
+
⇌
3
Cr
2
+
\text{Cr} + 2\text{Cr}^{3+} \rightleftharpoons 3\text{Cr}^{2+}
Cr
+
2
Cr
3
+
⇌
3
Cr
2
+
. The number of cells with different
E
∘
E^\circ
E
∘
and 'n' but same value of
Δ
G
∘
\Delta G^\circ
Δ
G
∘
can be made: (Given,
E
Cr
3
+
/
Cr
2
+
∘
=
−
0.40
V
E_{\text{Cr}^{3+}/\text{Cr}^{2+}}^\circ = -0.40 \text{ V}
E
Cr
3
+
/
Cr
2
+
∘
=
−
0.40
V
,
E
Cr
3
+
/
Cr
∘
=
−
0.74
V
E_{\text{Cr}^{3+}/\text{Cr}}^\circ = -0.74 \text{ V}
E
Cr
3
+
/
Cr
∘
=
−
0.74
V
and
E
Cr
2
+
/
Cr
∘
=
−
0.91
V
E_{\text{Cr}^{2+}/\text{Cr}}^\circ = -0.91 \text{ V}
E
Cr
2
+
/
Cr
∘
=
−
0.91
V
) a. 1 b. 2 c. 3 d. 4
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