Chlorine gas is produced in the laboratory by the reaction of hydrochloric acid, HCl(aq) , with manganese(IV) oxide, MnO2(s) :
MnO2(s)+4HCl(aq)→MnCl2(aq)+Cl2(g)+2H2O(l)
A 17.4 g sample of manganese(IV) oxide was added to 0.100 dm3 of 10.0 mol dm−3 hydrochloric acid, and the mixture was heated until the reaction was complete.