Let a=⟨3,−2,1⟩ and b=⟨k,4,−2⟩, where k is a real number.
a. (i) Calculate a⋅b when k=1.
b. (ii) Find the value of k for which a and b are perpendicular.
c. (iii) For the value of k obtained in part (ii), determine the angle between a and b+a, giving your answer in degrees to the nearest whole number.