Bohr's correspondence principle states that in the limit of large quantum numbers the classical power radiated in the fundamental is equal to the product of the quantum energy (ℏω0) and the reciprocal mean lifetime of the transition from principal quantum number n to (n−1).
(a) Using nonrelativistic approximations, show that in a hydrogen-like atom the transition probability (reciprocal mean lifetime) for a transition from a circular orbit of principal quantum number n to (n−1) is given classically by
τ1=32ℏce2(ℏcZe2)4ℏmc2n51
(b) For hydrogen compare the classical value from part a with the correct quantum-mechanical results for the mean lives of the transitions 2p→1s (1.6×10−9 s), 4f→3d (7.3×10−8 s), 6h→5g (6.1×10−7 s).