Introduction to Quantum Mechanics · Problem 7.2

Time-Independent Perturbation Theory — David J. Griffiths

Physics — Quantum Mechanics · nondegenerate_perturbation_theory

Problem

For the harmonic oscillator [V(x)=(1/2)kx2][V(x) = (1/2)kx^2], the allowed energies are En=(n+1/2)ℏω,(n=0,1,2,…),E_n = (n + 1/2)\hbar\omega, \quad (n = 0, 1, 2, \ldots), where ω=k/m\omega = \sqrt{k/m} is the classical frequency. Now suppose the spring constant increases slightly: k→(1+ϵ)kk \to (1 + \epsilon)k. (Perhaps we cool the spring, so it becomes less flexible.) (a) Find the *exact* new energies (trivial, in this case). Expand your formula as a power series in ϵ\epsilon, up to second order. (b) Now calculate the first-order perturbation in the energy, using Equation 7.9. What is H′H' here? Compare your result with part (a). *Hint:* It is not necessary—in fact, it is not *permitted*—to calculate a single integral in doing this problem.

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