Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 4.6-8

ALTERNATIVE FORMULATIONS AND LEGENDRE TRANSFORMATIONS

Physics — Statistical Mechanics · van-der-waals-reversible-work

Problem

Assume that 1 mole of an ideal van der Waals fluid is expanded isothermally, at temperature ThT_h, from an initial volume ViV_i to a final volume VfV_f. A thermal reservoir at temperature TcT_c is available. Apply equation 4.9 to a differential process and integrate to calculate the work delivered to a reversible work source. Corroborate by overall energy and entropy conservation. Hint: Remember to add the direct work transfer P dVP\,dV to obtain the total work delivered to the reversible work source (as in equation 4.9).

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