Chemistry

Chemistry

Problem

Standard reduction potentials at 25 °C: Ag++e−→Ag(s)Ag^{+} + e^{-} \rightarrow Ag(s) E∘=+0.80 VE^\circ = +0.80\,\text{V} Ni2++2 e−→Ni(s)Ni^{2+} + 2\,e^{-} \rightarrow Ni(s) E∘=−0.25 VE^\circ = -0.25\,\text{V} A galvanic cell is assembled with a silver electrode in 1.0 M Ag+1.0\,\text{M}\,Ag^{+} and a nickel electrode in 1.0 M Ni2+1.0\,\text{M}\,Ni^{2+}. a. Determine which electrode is the anode. b. Determine whether that electrode is positive or negative during spontaneous operation.

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