Four beakers each contain 100mL of aqueous calcium nitrate at the indicated concentration. In which beaker must the fluoride ion concentration be highest to start forming CaF2 precipitate at 25∘C? (Ksp(CaF2) is the same in all cases.)
a) [Ca2+] = 0.010\;\text{M}
b) [Ca2+] = 0.0010\;\text{M}
c) [Ca2+] = 0.020\;\text{M}
d) [Ca2+] = 0.0050\;\text{M}