Chemistry

Chemistry

Problem

Which of the following reaction is expected never to be spontaneous :- (1) 2O3→3O22\text{O}_3 \rightarrow 3\text{O}_2 ΔH=−ve,ΔS=+ve\Delta H = -\text{ve}, \Delta S = +\text{ve} (2) Mg+H2→MgH2\text{Mg} + \text{H}_2 \rightarrow \text{MgH}_2 ΔH=−ve,ΔS=−ve\Delta H = -\text{ve}, \Delta S = -\text{ve} (3) Br2(ℓ)→Br2(g)\text{Br}_2(\ell) \rightarrow \text{Br}_2(\text{g}) ΔH=+ve,ΔS=+ve\Delta H = +\text{ve}, \Delta S = +\text{ve} (4) 2Ag+3N2→2AgN32\text{Ag} + 3\text{N}_2 \rightarrow 2\text{AgN}_3 ΔH=+ve,ΔS=−ve\Delta H = +\text{ve}, \Delta S = -\text{ve}

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