Chemistry

Chemistry

Problem

The following standard reduction potentials are given: Zn2++2e−→^{2+}+2e^-\rightarrowZn, E∘=−0.76 VE^\circ=-0.76\,\text{V} Cu2++2e−→^{2+}+2e^-\rightarrowCu, E∘=+0.34 VE^\circ=+0.34\,\text{V} Consider the reaction under standard conditions: Zn(s)+(s)+Cu2+(aq)→^{2+}(aq)\rightarrowZn2+(aq)+^{2+}(aq)+Cu(s)(s). What is Ecell∘E^\circ_{\text{cell}} for this reaction, and is the reaction thermodynamically favored? a) Ecell∘=−0.42 V;E^\circ_{\text{cell}}=-0.42\,\text{V}; the reaction is not thermodynamically favored. b) Ecell∘=+0.42 V;E^\circ_{\text{cell}}=+0.42\,\text{V}; the reaction is thermodynamically favored. c) Ecell∘=+1.10 V;E^\circ_{\text{cell}}=+1.10\,\text{V}; the reaction is thermodynamically favored. d) Ecell∘=−1.10 V;E^\circ_{\text{cell}}=-1.10\,\text{V}; the reaction is not thermodynamically favored.

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