Introduction to Quantum Mechanics · Problem 4.54

Quantum Mechanics in Three Dimensions — David J. Griffiths

Physics — Quantum Mechanics · electron_inside_nucleus

Problem

What is the probability that an electron in the ground state of hydrogen will be found inside the nucleus? (a) First calculate the exact answer, assuming the wave function (Equation 4.80) is correct all the way down to r=0r = 0. Let bb be the radius of the nucleus. (b) Expand your result as a power series in the small number ϵ≡2b/a\epsilon \equiv 2b/a, and show that the lowest-order term is the cubic: P≈(4/3)(b/a)3P \approx (4/3)(b/a)^3. This should be a suitable approximation, provided that b≪ab \ll a (which it is). (c) Alternatively, we might assume that ψ(r)\psi(r) is essentially constant over the (tiny) volume of the nucleus, so that P≈(4/3)πb3∣ψ(0)∣2P \approx (4/3)\pi b^3 |\psi(0)|^2. Check that you get the same answer this way. (d) Use b≈10−15b \approx 10^{-15} m and a≈0.5×10−10a \approx 0.5 \times 10^{-10} m to get a numerical estimate for PP. Roughly speaking, this represents the "fraction of its time that the electron spends inside the nucleus."

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