Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 18.1-2

QUANTUM FLUIDS

Physics — Statistical Mechanics · fermion-pre-gas-entropy

Problem

The entropy of a system is given by S=−kB∑jfjln⁡fjS = -k_B \sum_j f_j \ln f_j, where fjf_j is the probability of a microstate of the system. Each microstate of the fermion pre-gas model is described by specifying the occupation of all six orbital states. aa) Show that there are 26=642^6 = 64 possible microstates of the model system, and that there are therefore 64 terms in the expression for the entropy. bb) Show that this expression reduces to S=−kB∑n,mfnmln⁡fnmS = -k_B \sum_{n,m} f_{nm} \ln f_{nm} and that this equation contains only six terms. What special properties of the model effect this drastic reduction?

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