Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 9.3-2

FIRST-ORDER PHASE TRANSITIONS

Physics — Statistical Mechanics · clapeyron-solid-density

Problem

A long vertical column is closed at the bottom and open at the top; it is partially filled with a particular liquid and cooled to −5∘-5^\circC. At this temperature the fluid solidifies below a particular level, remaining liquid above this level. If the temperature is further lowered to −5.2∘-5.2^\circC the solid--liquid interface moves upward by 40 cm. The latent heat (per unit mass) is 2 cal/g, and the density of the liquid phase is 1 g/cm3^3. Find the density of the solid phase. Neglect thermal expansion of all materials. Hint: Note that the pressure at the original position of the interface remains constant. Answer: 2.6 g/cm32.6\text{ g/cm}^3

Browse the problem library