At 450K the reaction
2SO2(g)+O2(g)⇌2SO3(g)
is at equilibrium with
[SO2] =0.20M, [O2] =0.10M, and [SO3] =0.40M. A single disturbance is applied, and immediately afterward only the product concentration is observed to change, jumping to [SO3] =0.60M while the reactant concentrations are unchanged at that instant. Identify the most likely change that was made to the system.