Chemistry

Chemistry

Problem

1-Butanol (CH3_3CH2_2CH2_2CH2_2OH) has a significantly higher melting point than its constitutional isomer diethyl ether (CH3_3CH2_2OCH2_2CH3_3). Which statement best explains this observation? a) Diethyl ether is branched, decreasing its surface area and lowering its melting point relative to the linear 1-butanol. b) 1-Butanol has a larger molar mass than diethyl ether, resulting in stronger London dispersion forces and a higher melting point. c) 1-Butanol forms extensive hydrogen bonds between molecules, whereas diethyl ether cannot donate hydrogen bonds. d) Diethyl ether is more polar than 1-butanol, so its molecules repel one another more strongly, leading to a lower melting point.

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