In a titration mishap, 0.010mol of HCl is accidentally added to 100.0mL of each of the following NH3/NH4+ buffer solutions. In which buffer will all of the HCl be completely neutralized while leaving some NH3 unreacted?
a) 0.10M NH3 and 0.10M NH4+
b) 0.05M NH3 and 0.15M NH4+
c) 0.15M NH3 and 0.05M NH4+
d) 0.05M NH3 and 0.05M NH4+