Energy fluctuations in a solid at low temperatures. Consider a solid of N atoms in the temperature region in which the Debye T3 law is valid. The solid is in thermal contact with a heat reservoir. Use the results on energy fluctuations from Chapter 3 to show that the root mean square fractional energy fluctuation F is given by
F2=⟨(ε−⟨ε⟩)2⟩/⟨ε⟩2≈N0.07(Tθ)3.(57)
Suppose that T=10−2K; θ=200K; and N≈1015 for a particle 0.01 cm on a side; then F≈0.02. At 10−5K the fractional fluctuation in energy is of the order of unity for a dielectric particle of volume 1 cm3.