Statistical Mechanics · Problem 3.10

The Grand Canonical Ensemble — R. K. Pathria

Physics — Statistical Mechanics · helium-gas-thermodynamics

Problem

(a) The volume of a sample of helium gas is increased by withdrawing the piston of the containing cylinder. The final pressure PfP_f is found to be equal to the initial pressure PiP_i times (Vi/Vf)1.2(V_i/V_f)^{1.2}, ViV_i and VfV_f being the initial and final volumes. Assuming that the product PVPV is always equal to 23U\frac{2}{3}U, will (i) the energy and (ii) the entropy of the gas increase, remain constant or decrease during the process? (b) If the process were reversible, how much would the work done and the heat added in doubling the volume of the gas be? Take Pi=1P_i = 1 atm and Vi=1V_i = 1 m3^3.

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