Introduction to Quantum Mechanics · Problem 8.6

The Variational Principle — David J. Griffiths

Physics — Quantum Mechanics · variational_perturbation_theory

Problem

(a) Use the variational principle to prove that first-order non-degenerate perturbation theory always *overestimates* (or at any rate never *underestimates*) the ground state energy. (b) In view of (a), you would expect that the *second*-order correction to the ground state is always negative. Confirm that this is indeed the case, by examining Equation 7.15.

Related theory

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