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Chemistry
Chemistry
Problem
Rate constant for
n
n
n
th order reaction is given by :
K
⋅
t
=
1
(
n
−
1
)
[
C
A
1
−
n
−
C
0
1
−
n
]
K \cdot t = \frac{1}{(n-1)} [C_A^{1-n} - C_0^{1-n}]
K
⋅
t
=
(
n
−
1
)
1
[
C
A
1
−
n
−
C
0
1
−
n
]
Thus, for a reaction of
n
n
n
th order, the ratio of
t
1
/
2
t
3
/
4
\frac{t_{1/2}}{t_{3/4}}
t
3/4
t
1/2
is : a.
2
n
2^n
2
n
b.
2
n
−
1
2^{n-1}
2
n
−
1
c.
2
1
−
n
2^{1-n}
2
1
−
n
d.
2
n
−
1
−
1
4
n
−
1
−
1
\frac{2^{n-1} - 1}{4^{n-1} - 1}
4
n
−
1
−
1
2
n
−
1
−
1
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