Introduction to Quantum Mechanics · Problem 5.12

Identical Particles — David J. Griffiths

Physics — Quantum Mechanics · symmetrization_multielectron

Problem

(a) Suppose you could find a solution ψ(r1,r2,…,rZ)\psi(\mathbf{r}_1, \mathbf{r}_2, \ldots, \mathbf{r}_Z) to the Schrödinger equation (Equation 5.37), for the Hamiltonian in Equation 5.36. Describe how you would construct from it a completely symmetric function, and a completely antisymmetric function, which also satisfy the Schrödinger equation, with the same energy. What happens to the completely antisymmetric function if ψ(r1,r2,…,rZ)\psi(\mathbf{r}_1, \mathbf{r}_2, \ldots, \mathbf{r}_Z) is symmetric in (say) its first two arguments (r1↔r2\mathbf{r}_1 \leftrightarrow \mathbf{r}_2)? (b) By the same logic, show that a completely antisymmetric spin state for ZZ electrons is impossible, if Z>2Z > 2 (this generalizes Problem 5.10(a)).

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