Introduction to Quantum Mechanics · Problem 8.29

The Variational Principle — David J. Griffiths

Physics — Quantum Mechanics · existence_bound_states

Problem

Existence of Bound States. A potential "well" (in one dimension) is a function V(x)V(x) that is never positive (V(x)≤0V(x) \le 0 for all xx), and goes to zero at infinity (V(x)→0V(x) \to 0 as x→±∞x \to \pm\infty). (a) Prove the following Theorem: If a potential well V1(x)V_1(x) supports at least one bound state, then any deeper/wider well (V2(x)≤V1(x)V_2(x) \le V_1(x) for all xx) will also support at least one bound state. *Hint:* Use the ground state of V1V_1, ψ1(x)\psi_1(x), as a variational test function. (b) Prove the following Corollary: Every potential well in one dimension has a bound state. *Hint:* Use a finite square well (Section 2.6) for V1V_1. (c) Does the Theorem generalize to two and three dimensions? How about the Corollary? *Hint:* You might want to review Problems 4.11 and 4.51.

Browse the problem library