Introduction to Quantum Mechanics · Problem 7.40

Time-Independent Perturbation Theory — David J. Griffiths

Physics — Quantum Mechanics · second_order_degenerate_perturbation

Problem

If it happens that the square root in Equation 7.33 vanishes, then E+1=E−1E^1_+ = E^1_-; the degeneracy is not lifted at first order. In this case, diagonalizing the W\mathbf{W} matrix puts no restriction on α\alpha and β\beta and you still don't know what the "good" states are. If you need to determine the "good" states—for example to calculate higher-order corrections—you need to use second-order degenerate perturbation theory. (a) Show that, for the two-fold degeneracy studied in Section 7.2.1, the first-order correction to the wave function in degenerate perturbation theory is ψ1=∑m≠a,bαVma+βVmbE0−Em0ψm0.\psi^1 = \sum_{m \neq a,b} \frac{\alpha V_{ma} + \beta V_{mb}}{E^0 - E^0_m} \psi^0_m. (b) Consider the terms of order λ2\lambda^2 (corresponding to Equation 7.8 in the nondegenerate case) to show that α\alpha and β\beta are determined by finding the eigenvectors of the matrix W2\mathsf{W}^2 (the superscript denotes second order, not W\mathbf{W} squared) where [W2]ij=∑m≠a,b⟨ψi0∣H′∣ψm0⟩⟨ψm0∣H′∣ψj0⟩E0−Em0\left[\mathsf{W}^2\right]_{ij} = \sum_{m \neq a,b} \frac{\langle \psi^0_i | H' | \psi^0_m \rangle \langle \psi^0_m | H' | \psi^0_j \rangle}{E^0 - E^0_m} and that the eigenvalues of this matrix correspond to the second-order energies E2E^2. (c) Show that second-order degenerate perturbation theory, developed in (b), gives the correct energies to second order for the three-state Hamiltonian in Problem 7.39.

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