Introduction to Quantum Mechanics · Problem 5.32

Identical Particles — David J. Griffiths

Physics — Quantum Mechanics · polarized_electron_gas

Problem

Consider a free electron gas (Section 5.3.1) with unequal numbers of spin-up and spin-down particles (N+N_+ and N−N_- respectively). Such a gas would have a net magnetization (magnetic dipole moment per unit volume) M=−(N+−N−)VμBk^=Mk^,\mathbf{M} = -\frac{(N_+ - N_-)}{V} \mu_B \hat{k} = M\hat{k}, where μB=eℏ/2me\mu_B = e\hbar/2m_e is the Bohr magneton. (The minus sign is there, of course, because the charge of the electron is negative.) (a) Assuming that the electrons occupy the lowest energy levels consistent with the number of particles in each spin orientation, find EtotE_{\text{tot}}. Check that your answer reduces to Equation 5.56 when N+=N−N_+ = N_-. (b) Show that for M/μB≪ρ≡(N++N−)/VM/\mu_B \ll \rho \equiv (N_+ + N_-)/V (which is to say, ∣N+−N−∣≪(N++N−)|N_+ - N_-| \ll (N_+ + N_-)), the energy density is 1VEtot=ℏ2(3π2ρ)5/310π2m[1+59(MρμB)2].\frac{1}{V} E_{\text{tot}} = \frac{\hbar^2 (3\pi^2 \rho)^{5/3}}{10\pi^2 m} \left[ 1 + \frac{5}{9} \left( \frac{M}{\rho \mu_B} \right)^2 \right]. The energy is a minimum for M=0M = 0, so the ground state will have zero magnetization. However, if the gas is placed in a magnetic field (or in the presence of interactions between the particles) it may be energetically favorable for the gas to magnetize. This is explored in Problems 5.33 and 5.34.

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