Thermal Physics · Problem 6

Ideal Gas — Charles Kittel & Herbert Kroemer

Physics — Statistical Mechanics · entropy-of-mixing

Problem

Entropy of mixing. Suppose that a system of NN atoms of type A is placed in diffusive contact with a system of NN atoms of type B at the same temperature and volume. Show that after diffusive equilibrium is reached the total entropy is increased by 2Nlog⁡22N \log 2. The entropy increase 2Nlog⁡22N \log 2 is known as the entropy of mixing. If the atoms are identical (A≡BA \equiv B), show that there is no increase in entropy when diffusive contact is established. The difference in the results has been called the Gibbs paradox.

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