We would like to show that θ^⋅L generates rotations about the axis parallel to θ^. Let δθ be an infinitesimal rotation parallel to θ.
(1) Show that when a vector r is rotated by an angle δθ, it changes to r+δθ×r. (It might help to start with r⊥δθ and then generalize.)
(2) We therefore demand that (to first order, as usual)
ψ(r)U[R(δθ)]⟶ψ(r−δθ×r)=ψ(r)−(δθ×r)⋅∇ψ
Comparing to U[R(δθ)]=I−(iδθ/ℏ)Lθ^, show that Lθ^=θ^⋅L.