Chemistry

Chemistry

Problem

For the aqueous equilibrium reaction N2O4(aq)⇌2 NO2(aq)\mathrm{N_2O_4(aq) \rightleftharpoons 2\,NO_2(aq)} a large volume of water is suddenly added while temperature is held constant. Which statement best predicts the immediate response of the system? a) The equilibrium shifts toward formation of N2O4\mathrm{N_2O_4} because dilution favors the side with fewer dissolved particles. b) The position of equilibrium is unchanged because all concentrations are reduced proportionally, leaving the reaction quotient equal to KK.},{ c) The equilibrium shifts toward formation of NO2\mathrm{NO_2} because producing more dissolved particles offsets the dilution. d) The equilibrium constant decreases when water is added, so the reaction shifts toward reactants until Q=KQ=K again.

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