Statistical Mechanics · Problem 6.13

Ideal Bose Systems — R. K. Pathria

Physics — Statistical Mechanics · effusion-maxwellian-gas

Problem

Consider the effusion of molecules of a Maxwellian gas through an opening of area aa in the walls of a vessel of volume VV. (a) Show that, while the molecules inside the vessel have a mean kinetic energy 32kT\frac{3}{2}kT, the effused ones have a mean kinetic energy 2kT2kT, TT being the quasi-static equilibrium temperature of the gas. (b) Assuming that the effusion is so slow that the gas inside is always in a state of quasi-static equilibrium, determine the manner in which the density, the temperature and the pressure of the gas vary with time.

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