A 500 mL buffer solution is 0.40 M in HCOOH and 0.20 M in NaHCOO. Which single addition would most likely exhaust the buffer toward pH increase?
a) Adding 25mL of 0.10MNaOH(aq)
b) Adding 5mL of 1.0MNaOH(aq)
c) Adding 50mL of 0.10MHCl(aq)
d) Adding 5mL of 1.0MHCl(aq)