Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 13.2-8

IRREVERSIBLE THERMODYNAMICS

Physics — Statistical Mechanics · chemical-reactions-ideal-gases

Problem

Apply equation 13.8 to a single-component general ideal gas (of species

j

). Evaluate

\mu_j

for the single-component ideal gas by equation 13.4 (note that by equation 13.3 constant

U

implies constant

T

), and in this way obtain an expression for

\phi_j